Published May 13, 2025 | Version v1
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Efficient Synthesis of 2-Amino-4H-benzo[b]pyrans via Copper-periodic Mesoporous Organosilica Nanocomposites Catalyst in Aqueous Media

  • 1. Department of Chemistry, Graduate University of Advanced Technology, Kerman, Iran
  • 2. Department of Chemical Engineering, Sirjan University of Technology, Sirjan, Iran
  • 3. Central Lab, Vali-e-Asr University, Rafsanjan, Iran, 77176
  • 4. Organic Chemistry Department of Materials Science and Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology Kerman, Iran

Description

Acta Chim. Slov. 2025, 72, 339–346. DOI: 10.17344/acsi.2024.8962

Abstract

In this study, the efficient method was introduced for the preparation of copper-periodic mesoporous organosilica nanocomposites (Cu@MOS NCs) as a high performance heterogeneous nanocatalyst. Then the nanocomposite was characterized with various methods such as X-ray diffraction (XRD), BET analysis, SEM and EDS microscopy and thermogravimetric analysis (TGA). The Cu@MOS NC as nanocatalyst was applied for one-pot three component reactions of aromatic aldehydes, dimedone, and malononitrile for the effective and green synthesis of 2-amino-4H-benzo[b]pyran derivatives in high yields, with operational simplicity, environmental friendliness, wide applicability and reusability and easy recovery of the catalyst.

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Other
Acta Chim. Slov. 2025, 72, 339–346
DOI
10.17344/acsi.2024.8962
PMID
40538214

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Journal article: 10.17344/acsi.2024.8962 (DOI)