Published March 5, 2026 | Version 1.0

Structural investigations of the XeF2–PtF5 system: crystal structures of [Xe2F3][PtF6]·XeF2, [Xe2F3][PtF6], and [XeF][PtF6]

  • 1. Extreme Conditions Chemistry Laboratory (ECCL K2), Jožef Stefan Institute, Jamova cesta 39, 1000 Ljubljana, Slovenia; Jožef Stefan International Postgraduate School, Jamova cesta 39, 1000 Ljubljana, Slovenia

Description

Acta Chimica Slovenica, 2026, 73, 62–69. DOI: 10.17344/acsi.2026.9768

Abstract

The XeF2–PtF5 system was reinvestigated by exploring reactions in either anhydrous HF or at elevated temperatures. This approach enabled the structural characterization of four members of the system, namely [Xe2F3][PtF6]·XeF2(mC120), [Xe2F3][PtF6]·XeF2(oP120), [Xe2F3][PtF6], and [XeF][PtF6](mP108), by means of single-crystal X-ray diffraction and low-temperature Raman spectroscopy.

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Other
Acta Chimica Slovenica, 2026, 73, 62–69
DOI
10.17344/acsi.2026.9768

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Is identical to
Journal article: 10.17344/acsi.2026.9768 (DOI)
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Dataset: 10.5281/zenodo.18428036 (DOI)